Thank you for your replies, I have tried changing the jaws over even 'though they are numbered, it made no difference other than confirming it seems to be the slot. I have dismantled as far as I can again today and for a while the problem seemed to be worse as the jaw seized 14 way in! Taking it out put things back to 'Normal' i.e. binding.
I could see no obvious binding spots on any of the jaws nor anything 'untoward' (to my untrained eye) down the slots.
The worm/screw in the difficult slot is very loose, I surmise that the two part thread on this screw (in which the key fits) has some sort of retaining lug half way down the slot.
I can't see how to get the plug (4 in No. corresponding to the jaws) at the rear of the chuck, out there doesn't appear to be a way.
Thanks again guys, all help gratefully accepted.