Posted by Paul Lousick on 04/08/2015 23:46:35:
"Should not be a problem using it in contact with steam, its the hot water you don't want it to come into contact with so don't use on the boiler or fittings below water level".
Can someone please explain the problem with using brass fittings ? Many model suppliers for boiler fittings are selling brass whistles, water gauges, etc. Are these OK ?
Paul.
It's down to the dissimilar metal problem. This chart illustrates the problem

Basically if 2 dissimilar metals are placed together they form a battery cell when damp if there is something in the water that allows it to behave as an electrolyte. There usually is. The metals sit a different voltages / potentials. The same applies when metals are separated in water. The effect is worse when the metals are carrying current which is why you might come across electrical parts described as passivated but as you can see from the chart the effect can't be totally ignored unless the metals are the same and not oxidised to varying degrees. This is why gold and other metal plated contacts in electronic items are often used.
Brass is supposed to be a solid solution of 2:1 copper to zinc. It may well be when the ratio is correct. I have seen comments that it's ok if it's "good brass", The general answer seems to be to add small amounts of tin or even aluminium to it – a bit like bronze but not bronze. This is what gun metal is but it seems brass with 1% tin can be used, sort of sub gun metal which in turn is sub bronze.
Steam should be ok in brass? LOL. It's reckoned to be pure water which can't form an electrolyte. LOL because that is a bit of a dubious statement. De ionised water can't for a very short period even when just exposed to air as it takes up carbon dioxide rapidly and form an acid. Distilled water is stable but not pure. One answer to using brass might be to only fill the boiler with distilled water which some do anyway. Ships use sacrificial anodes even with the correct alloys as salt water is a good electrolyte. Tap water varies across the country.
I have also seen "live steam" comments that brass is ok up to 2 bar and a problem above that. I suspect that is a dubious statement as well. Effects are likely to depend on temperature so all that will happen is that the rate will change. It would be interesting to see the rate of change with temperature but there are some extremely old working low pressure steam engines about that use lots of brass. I'd guess they use a tinned brass as I suspect domestic taps etc do. Pass really as it's an area where it's hard to find definitive information – only that such and such is better in some respect.
John
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